Observing the chain stretch transition in a highly entangled polyisoprene melt using transient extensional rheometry

نویسندگان
چکیده

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Observing the chain stretch transition in a highly entangled polyisoprene melt using transient extensional rheometry

We measure the viscoelastic properties of a highly entangled narrow molecular weight polyisoprene melt with approximately 280 entanglements per chain in steady and transient shear and in elongational ows. The storage and loss moduli of the melt are found to be well described by the Milner and McLeish model. The relaxation modulus G(t, γ) is measured using stress relaxation after a sudden sheari...

متن کامل

Microfluidic extensional rheometry using a hyperbolic contraction geometry

Microfluidic devices are ideally suited for the study of complex fluids undergoing large deformation rates in the absence of inertial complications. In particular, a microfluidic contraction geometry can be utilized to characterize the material response of complex fluids in an extensionally-dominated flow, but the mixed nature of the flow kinematics makes quantitative measurements of material f...

متن کامل

Entangled chain dynamics of polymer knots in extensional flow.

We formulate a coarse-grained molecular-dynamics model of polymer chains in solution that includes hydrodynamic interactions, thermal fluctuations, nonlinear elasticity, and topology-preserving solvent mediated excluded volume interactions. The latter involve a combination of potential forces with explicit geometric detection and tracking of chain entanglements. By solving this model with numer...

متن کامل

Constant Force Extensional Rheometry of Polymer Solutions

We revisit the rapid stretching of a liquid filament under the action of a constant imposed tensile force, a problem which was first considered by Matta & Tytus [JNNFM vol. 35, pp 215-229, 1990]. A liquid bridge formed from a viscous Newtonian fluid or from a dilute polymer solution is first established between two cylindrical disks. The upper disk is held fixed and may be connected to a force ...

متن کامل

Capillary breakup extensional rheometry of a wormlike micellar solution

The behaviour of a cetylpyridinium chloride/sodium salicylate wormlike micellar system undergoing capillary breakup is investigated experimentally. The transient elongational flow induced in a thinning thread is used to study the apparent viscosity and effective relaxation time of the micellar network in extension. The sensitivity of the material response to initial conditions and deformation h...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Journal of Rheology

سال: 2009

ISSN: 0148-6055,1520-8516

DOI: 10.1122/1.3208073